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Chemical Storage Guidelines from The CDC

If you need a set of chemical storage guidelines meet OSHA and safety needs in your lab, school, manufacturing or storage facility, this page should provide the template you need.

Guidelines for Safe Chemical Storage

Safe chemical handling requires routine inspections of chemical storage areas and maintenance of stringent inventory control. The inherent hazards of chemicals can be reduced by minimizing the quantity of chemicals on hand. However, when chemicals must be used, proper storage and handling can reduce or eliminate associated risks. All chemical storage areas and cabinets should be inspected at least annually and any unwanted or expired chemicals should be removed.

Typical storage considerations may include temperature, ignition control, ventilation, segregation and identification. Proper segregation is necessary to prevent incompatible materials from inadvertently coming into contact. A physical barrier and/or distance is effective for proper segregation.

Proper storage information can usually be obtained from the Material Safety Data Sheet (MSDS), label, or other chemical reference material. As required by 29 CFR 1910.1200, an MSDS must be on hand for every hazardous chemical in your workplace. MSDSs must be provided by the manufacturer or distributor of chemicals purchased. MSDSs are also available through the LINDEN system, CDC's Chemical Tracking System. This system tracks CDC's chemical inventory and includes MSDSs for most chemicals in the inventory. The Internet can also be used to find MSDSs. For a fast search for an MSDS on the Internet, go to the CDC Intranet, select "Databases", then select "Scientific Information", and then "Material Safety Datasheets". This site provides specific manufacturer information as well as generic information.
 

Keys for safe chemical storage:
 

Table 1. Examples of Incompatible Chemicals

The following list is not a complete listing of incompatible materials. It contains some of the more common incompatible materials. Always research materials you work with in order to work safely in the lab.
 

Chemicals listed in Column A should not be stored with or used near items in Column B.

 

Column A Column B
Acetic acid Chromic acid, nitric acid, hydroxyl compounds, ethylene glycol, perchloric acid, peroxides, permanganates
Acetic anhydride Hydroxyl-containing compounds such as ethylene glycol, perchloric acid
Acetone Concentrated nitric and sulfuric acid mixtures, hydrogen peroxide
Acetylene Chlorine, bromine, copper, fluorine, silver, mercury
Alkali and alkaline earth metals such as powdered magnesium, sodium, potassium Water, carbon tetrachloride or other chlorinated hydrocarbons, carbon dioxide, halogens
Ammonia (anhydrous) Mercury, halogens, calcium hypochlorite, hydrofluoric acid
Ammonium nitrate Acids, metal powders, flammable liquids, chlorates, nitrites, sulfur, finely divided organic or combustible materials
Aniline Nitric acid, hydrogen peroxide
Arsenical materials Any reducing agent
Azides Acids, heavy metals and their salts, oxidizing agents
Calcium oxide Water
Carbon, activated All oxidizing agents, calcium hypochlorite
Carbon tetrachloride Sodium
Chlorates Ammonium salts, acids, metal powders, sulfur, finely divided organic or combustible material
Chlorine dioxide Ammonia, methane, phosphine, hydrogen sulfide
Chromic acid and chromium trioxide Acetic acid, alcohol, camphor, glycerol, naphthalene, flammable liquids in general
Copper Acetylene, hydrogen peroxide
Cumene hydroperoxide Acids (organic or inorganic)
Cyanides Acids
Flammable liquids Ammonium nitrate, chromic acid, hydrogen peroxide, nitric acid, sodium peroxide, halogens, other oxidizing agents
Fluorine All other chemicals
Hydrides Water
Hydrocarbons (e.g., butane, propane, benzene) Fluorine, chlorine, bromine, chromic acid, peroxides
Hydrocyanic acid Nitric acid, alkalis
Hydrofluoric acid (anhydrous) Ammonia (aqueous or anhydrous)
Hydrogen peroxide Copper, chromium, iron, most metals or their salts, any flammable liquid (i.e., alcohols, acetone), combustible materials, aniline, nitromethane
Hydrogen sulfide Fuming nitric acid, oxidizing gases
Hypochlorites Acids, activated carbon
Iodine Acetylene, ammonia (aqueous or anhydrous), hydrogen
Mercury Acetylene, fulminic acid, ammonia
Metal hydrides Acids, water
Nitrates Acids
Nitric acid (concentrated) Acetic acid, acetone, alcohol, aniline, chromic acid, hydrocyanic acid, hydrogen sulfide, flammable liquids, flammable gases, copper, brass, any heavy metals
Nitrites Acids
Nitroparaffins Inorganic bases, amines
Oxalic acid Mercury and silver and their salts
Oxygen Oils, grease, hydrogen; flammable liquids, solids, or gases
Perchloric acid Acetic anhydride, alcohol, bismuth, paper, wood, grease, oils
Permanganates Concentrated sulfuric acid, glycerol, ethylene glycol, benzaldehyde
Peroxides, organic Acids (organic or mineral), avoid friction, store cold
Phosphorus, white Air, oxygen, alkalis, reducing agents
Potassium Carbon tetrachloride, carbon dioxide, water
Potassium chlorate Sulfuric and other acids, ammonium salts, metal powders, sulfur, finely divided organics, combustibles
Potassium perchlorate (see also chlorates) Sulfuric and other acids
Potassium permanganate Glycerol, ethylene glycol, benzaldehyde, sulfuric acid
Silver and silver salts Acetylene, oxalic acid, tartaric acid, ammonium compounds, fulminic acid
Sodium Carbon tetrachloride, carbon dioxide, other chlorinated hydrocarbons, water
Sodium nitrate Ammonium nitrate and other ammonium salts
Sodium peroxide Ethyl or methyl alcohol, glacial acetic acid, acetic anhydride, benzaldehyde, carbon disulfide glycerin, ethylene glycol, ethyl acetate, methyl acetate, furfural
Sulfides Acids
Sulfuric acid Chlorates, perchlorates, permanganates

Adapted from Prudent Practices in the Laboratory: Handling and Disposal of Chemicals, National Research Council, 1995, with additions from OHS.
 

Table 2. Basic Chemical Segregation

 

Hazard Class of Chemical Recommended Storage Method Examples Incompatibilities
Compressed gases - Flammable Store in a cool, dry area, away from oxidizing gases. Securely strap or chain cylinders to a wall or bench. Methane Hydrogen

Acetylene Propane

Oxidizing and toxic compressed gases, oxidizing solids.
Compressed gases - Oxidizing Store in a cool, dry area, away from flammable gases and liquids. Securely strap or chain cylinders to a wall or bench. Oxygen

Chlorine

Bromine

Flammable gases
Compressed gases - Poisonous Store in a cool, dry area, away from flammable gases and liquids. Securely strap or chain cylinders to a wall or bench. Carbon monoxide

 

Hydrogen sulfide

Nitrogen dioxide

Flammable and/or oxidizing gases.
Corrosives - Acids Store separately in acid storage cabinet. Segregate oxidizing acids (i.e., Chromic, nitric, sulfuric, and perchloric acids) from organic acids Acetic acid Phenol

 

Sulfuric acid Chromerge

Nitric acid

Perchloric acid

Chromic acid

Hydrochloric acid

Flammable liquids, flammable solids, bases, oxidizers
Corrosives - Bases Store in separate corrosive storage cabinet. Store solutions of inorganic hydroxides in labeled polyethylene containers. Ammonium hydroxide

 

Sodium hydroxide

Calcium hydroxide

Flammable liquids, oxidizers, poisons, and acids
Flammable Liquids Store in flammable storage cabinet and away from sources of ignition. Store highly volatile flammable liquids in an explosion-proof refrigerator. Acetone Benzene

 

Diethyl ether Methanol

Ethanol Toluene

Glacial acetic acid

Acids, bases, oxidizers, and poisons

 

Flammable Solids Store in a separate dry, cool area away from oxidizers, corrosives, flammable liquids Phosphorus, yellow

Calcium carbide

Picric acid

Benzoyl peroxide

Acids, bases, oxidizers, and poisons
General Chemicals - Non-reactive Store on general laboratory benches or shelving preferably behind glass doors and below eye level. Agar

 

Sodium chloride

Sodium bicarbonate

Most non-reactive salts

See specific MSDS.
Oxidizers Store in a spill tray inside a chemical storage cabinet. Separate from flammable and combustible materials. Ammonium persulfate

 

Ferric chloride

Iodine

Sodium hypochlorite

Benzoyl peroxide

Potassium permanganate

Potassium dichromate

The following are generally considered oxidizing substances: Peroxides, perchlorates, chlorates, nitrates, bromates, superoxides.

Separate from reducing agents, flammables, and combustibles.
Poisons/Toxic Compounds Store separately in vented, cool, dry area, in unbreakable chemically-resistant secondary containers and in accordance with the hazardous nature of the chemical. Aniline

 

Carbon tetrachloride

Chloroform

Cyanides

Heavy metals compounds, i.e., cadmium, mercury, osmium

Oxalic acid

Phenol

Formic acid

Flammable liquids, acids, bases, and oxidizers.

 



 

See specific MSDS.

Water-Reactive Chemicals Store in dry, cool location, protect from water fire sprinkler. Sodium metal

 

Potassium metal

Lithium metal

Lithium aluminum hydride

Separate from all aqueous solutions and oxidizers.
Carcinogens Label all containers as "Cancer Suspect Agents". Store according to the hazardous nature of the chemical, using appropriate security when necessary. Benzidine

 

Beta-naphthylamine

Benzene

Methylene chloride

Beta-propiolactone

See specific MSDS.
Teratogens Label all containers as "Suspect Reproductive Hazard". Store according to the hazardous nature of the chemical, using appropriate security when necessary. Lead and mercury compounds

 

Benzene

Aniline

See specific MSDS.
Peroxide-Forming Chemicals Store in air-tight containers in a dark, cool, dry area. See Table 3 for recommended storage time limits. Diethyl ether

 

Acetaldehyde

Acrylonitrile

See specific MSDS.
Strong Reducing Agents Store in cool, dry, well-ventilated location. Water reactive. Segregate from all other chemicals. Acetyl chloride

Thionyl chloride

Maleic anhydride

Ferrous sulfide

See specific MSDS.

 

Table 3. Suggested Storage Time Limits for Common Peroxidizable Compounds
 

Under proper conditions, these chemicals will form explosive peroxides which can be detonated by shock or heat.

 

MOST DANGEROUS: Discard after 3 months.

Peroxide formation hazard during storage.

Diisopropyl ether

Divinyl acetylene

Isopropyl ether

Potassium metal

Sodium amide

Vinylidene chloride

DANGEROUS: Discard after one year.

Peroxide formation hazard during storage and on concentration (i.e., distillation) of compound.

Acetal

Acetaldehyde

Cumene

Cyclohexene

Diacetylene

Dicyclopentadiene

Diethyl ether

1,4-Dioxane

Ethylene glycol dimethyl ether

Methyl acetylene

Methyl cyclopentane

Methyl isobutyl ketone

Tetrahydrofuran

Tetrahydronaphthalene

Vinyl ethers

DANGEROUS: Discard after one year.

Peroxide formation causes initiation of hazardous polymerization.

Acrylic acid

Acrylonitrile

1,3-Butadiene

2-Butanol

Chloroprene

Chlorotrifluoroethylene

Methyl methacrylate

2-Propanol

Styrene

Tetrafluoroethylene

Vinyl acetate

Vinyl acetylene

Vinyl chloride

Vinyl pyridine

 

Other Safety Tips:
 

 

This page was updated on 9-Feb-2009